Tritium gas, its hydrogen gas with 2 extra neutrons in the atom this makes it mildly radioactive emitting beta radiation, if you inhale it it can be quite dangerous. Luckily there are a lot of tools we use to protect against this such as gas masks and ventilated suits.
For modern nuclear power stations, it is the waste disposal. There is no good solution for the long-term storage of radioactive waste yet and it is going to cost a lot of money to make sure it is done right.
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